全文获取类型
收费全文 | 19486篇 |
免费 | 3652篇 |
国内免费 | 2887篇 |
专业分类
化学 | 14780篇 |
晶体学 | 344篇 |
力学 | 998篇 |
综合类 | 172篇 |
数学 | 1964篇 |
物理学 | 7767篇 |
出版年
2024年 | 37篇 |
2023年 | 453篇 |
2022年 | 579篇 |
2021年 | 840篇 |
2020年 | 1001篇 |
2019年 | 974篇 |
2018年 | 799篇 |
2017年 | 813篇 |
2016年 | 1100篇 |
2015年 | 1126篇 |
2014年 | 1362篇 |
2013年 | 1672篇 |
2012年 | 1991篇 |
2011年 | 2043篇 |
2010年 | 1430篇 |
2009年 | 1337篇 |
2008年 | 1454篇 |
2007年 | 1218篇 |
2006年 | 1040篇 |
2005年 | 835篇 |
2004年 | 648篇 |
2003年 | 502篇 |
2002年 | 419篇 |
2001年 | 328篇 |
2000年 | 286篇 |
1999年 | 291篇 |
1998年 | 216篇 |
1997年 | 174篇 |
1996年 | 187篇 |
1995年 | 140篇 |
1994年 | 131篇 |
1993年 | 112篇 |
1992年 | 108篇 |
1991年 | 87篇 |
1990年 | 57篇 |
1989年 | 59篇 |
1988年 | 36篇 |
1987年 | 26篇 |
1986年 | 35篇 |
1985年 | 29篇 |
1984年 | 9篇 |
1983年 | 7篇 |
1982年 | 10篇 |
1981年 | 4篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1959年 | 1篇 |
1957年 | 6篇 |
1937年 | 1篇 |
1936年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
52.
BP神经网络在上海住宅市场需求预测中的应用 总被引:5,自引:0,他引:5
人工神经网络是近期发展最快的人工智能领域研究成果之一 ,本文在介绍 BP神经网络的有关原理的基础上 ,建立了一个上海住宅市场的 BP神经网络模型 ,并通过该模型对上海住宅市场的需求进行了预测和分析 .分析结果表明人工神经网络方法在住宅市场需求预测中的应用是可行的并且是有效的 . 相似文献
53.
Two quantities ηrel and are applied to study the nonideal acetone–water association mixture. An all-atom acetone model and a TIP5P water model have been adopted for molecular dynamics simulation. We study the transport properties of the system comparing the 's of strong hydrogen bond and weak contact based on transport properties, MD simulations together with NMR experimental data and find good agreement of concentration dependence, which exhibits the cooperation effect. 相似文献
54.
The Mannich-type reaction of imines with (1-methoxy-2-methylpropenyloxy)trimethylsilane and aza-Diels-Alder reaction of imines with Danishefsky's diene can be carried out in scCO2 in the presence of lithium heptadecafluorooctanesulfonate which offer a way to synthesize β-amino carbonyl compounds and nitrogen-containing six-membered ring compounds under environmentally benign conditions. 相似文献
55.
Seiichi Nishizawa Tomoyuki Kamaishi Tomoyuki Yokobori Ryo Kato Ying-Yu Cui Takeshi Shioya Norio Teramae 《Analytical sciences》2004,20(11):1559-1565
Facilitated SO4(2-) transfers by hydrogen bond-forming ionophores are investigated across the nitrobenzene (NB)-water interface by using polarography with a dropping electrolyte electrode. Bis-thiourea 1, alpha,alpha'-bis(N'-p-nitrophenylthioureylene)-m-xylene, is found to significantly facilitate the transfer of the highly hydrophilic SO4(2-) whereas its counterpart, N-(p-nitrophenyl)-N'-propylthiourea (ionophore 2), cannot. In contrast to the predominant formation of a 1:1 complex with SO4(2-) in the bulk NB phase, the SO4(2-) transfer assisted by 1 is indeed based on the formation of a 1:2 complex between SO4(2-) and ionophore, even under the condition of [SO4(2-)]aq > [1]org. Such an exclusive formation of the 1:2 (SO4(2-) to ionophore) complex at the NB-water interface is not observed with structurally similar bis-thiourea 3, alpha,alpha'-bis(N'-phenylthioureylene)-m-xylene, where p-nitrophenyl moietes of bis-thiourea 1 are simply replaced by phenyl groups. The facilitated transfer of SO4(2-) with bis-thiourea 1 is further compared to that of HPO4(2-) and H2PO4- across the NB-water interface, which was previously shown to be assisted by 1 through the formation of the 1:1 and 2:1 (anion to ionophore) complexes, respectively. On the basis of these examinations, unique binding behaviors of hydrogen bond-forming ionophores at the NB-water interface are discussed, with a view towards development of ionophore-based anion-selective chemical sensors. 相似文献
56.
Stable aminoxyls and an iminoxyl were observed by spin trapping and EPR techniques during the nitration of coumarins containing a hydroxy group by nitric oxide. The trapped free radicals are deduced to be the resonance stabilized phenoxy-like radicals. The mechanisms for the nitrations are suggested. 相似文献
57.
Study on the Superhydrophilicity of the SiO2-TiO2 Thin Films Prepared by Sol-Gel Method at Room Temperature 总被引:2,自引:0,他引:2
Dasen Ren Xiaoli Cui Jie Shen Qun Zhang Xiliang Yang Zhuangjian Zhang Lu Ming 《Journal of Sol-Gel Science and Technology》2004,29(3):131-136
Nanoscale SiO2-TiO2 composite thin films with the thickness of about 100 nm were prepared by sol-gel method at room temperature in air. The chemical states of the elements on the surface and near the surface were measured by XPS. The results showed that the Ti on/near the surface of the thin films existed not only as TiO2 but also as Ti2O3. Part of the TiO2 was changed to Ti2O3 after UV irradiation. The crystalline structure of the TiO2 in the SiO2-TiO2 thin films was anatase with the crystallite size of 14–20 nm. It was found that the thin film prepared at room temperature in air has good superhydrophilic property and has strong adherence to the substrate. 相似文献
58.
介绍了一台10mm口径两级双程离轴放大系统,实现了对5mm×5mm口径光束的激光放大,耦合系统采用高功率LDA紧密侧面直接抽运棒状Nd:YLF方式。分析并实验研究了在不同抽运电流、放大脉冲与放大器LDA抽运时刻的不同延时及不同注入能量条件下,放大系统及光束每次放大时放大特性的规律。实验得到:在放大系统5mm×5mm软光阑处注入1.58mJ能量时,放大系统可输出129.2mJ能量,能量提取效率达到19.5%,满足该系统的设计指标。 相似文献
59.
60.
着重研究了多孔介质BISQ模型中慢纵波的基本特性.给出了BISQ模型下慢纵波速度 和衰减的低频近似公式.与Biot理论对比,BISQ模型中慢纵波的衰减随频率降低急剧增大, 且随喷射流长度的减小而增加;相速度随喷射流长度的减小而增加,其低频极限值不是零; 孔隙流体位移与固相骨架位移之比的幅值随喷射流长度的增加而减小,其相位特点与Biot模 型预测的不同;在流体与孔隙介质的边界上可产生更大的渗流.为对比,同时也给出快纵波 的行为.依据BISQ模型可推断:非黏滞流体饱和孔隙介质中不存在喷射流机理;BISQ模型中
关键词:
多孔介质
喷射流
慢纵波
动力协调 相似文献